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Pengaruh Konsentrasi Pendopingan Tembaga (Cu) Terhadap Sifat Fisis Nanomaterial Zno Menggunakan Metode Seed Mediated Hydrothermal
Copper (Cu) doped ZnO nanorod have been successfully grown on FTO surface using seed mediated hydrothermal method at 90°C for 8 hours. The grown copper doped ZnO material has been done using a precursor solution of 0.1 M Zinc Nitrate Hexahydrate (ZNH) and surfactant solution of 0.01 M Hexamethylenetetramine (HMT). The doping material was Copper (II) Nitrate Hydrate with various concentrations of 1 mM, 3 mM dan 5 mM. The samples were characterized by Field Emission Scanning Microscope (FESEM), Energy Dispersive X-ray (EDX), X-ray Diffraction (XRD) and UV-Vis Spectroscopy. The FESEM images showed that the geometrical shape of ZnO nanomaterial are nanorod. The effect of different concentrations of the copper solution result in a smaller nanorod ZnO shape because nanorod ZnO coated by copper. The spectrum of EDX 1 mM of the samples indicated that the weight percentages of 80%, 19% and 0.9% were respectively for Zn, O and Cu, meanwhile the percentages of the number of atoms were 50.622%, 48.962% and 0.414%, respectively for Zn, O and Cu. XRD patterns provided information that five diffraction peaks occured at 2θ: 31.8°, 34.2°, 36.2°, 47.5˚ dan 56.6˚ which indicated crystal orientation of ZnO nanorod, which were (100), (002), (101), (102) and (110) based on the result of the analysis using Eva Diffract Plus. The spectrum UV-Vis showed that the hexagonal nanorods were grown on the substrate and absorption peaks occurred in the range of 300-400 nm for all samples, the highest peak generated from 1 mM Cu-doped sample and a maximum absorption intensity of 10.2 a.u.
Keywords: ZnO nanomaterial, Seed Mediated Hydrothermal, Copper, physical properties.
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